Stereoselective synthesis of glycosides using (salen)Co catalysts as promoters.
نویسندگان
چکیده
The use of (salen)Co catalysts as a new class of bench-stable stereoselective glycosylation promoters of trichloroacetimidate glycosyl donors at room temperature is described. The conditions are practical and do not require the use of molecular sieves with products being isolated in good to high yields.
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متن کاملSpecial Seminar Assistant Professor
Research interests: Asymmetric catalysis for organic synthesis, including chiral diaminocarbene ligands and VHOIɅDVVHPEOHGGLQXFOHDU catalysts; development of VPDOOPROHFXOHDQWLɅFDQFHU agents; and total synthesis of complex molecules with interesting biological activities. Abstract Novel chiral Co-salen catalysts capable of self-assembly through hydrogen bonding have been developed. First, a self...
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ورودعنوان ژورنال:
- Chemical communications
دوره 51 43 شماره
صفحات -
تاریخ انتشار 2015